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Welcome to Professor Mehdi Amirnasr

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Office : Department of Chemistry, Isfahan University of Technology, Isfahan 8415683111, Iran Email : amirnasr[at]cc.iut.ac.ir Phone : +98-31-3391-3264 Fax : +98-31-3391-2350 Web Site : Mehdi Amirnasr

Professor

Research Fields : Synthesis and characterization of transition metal complexes with Schiff base ligands.

Transition metal complexes of deprotonated and neutral teradentate pyridine amide ligands.

Synthesis and structural characterization of new Cu(I) complexes of ligands of extended π character with potential application as photosensitizers

Transition metal complexes of N,S-donor ligands.and their biological activity

Electrochemistry and espectroelectrochemistry of coordination compounds

Teaching

Recent Publications

Inhibitive effect of sodium (E)-4-(4-nitrobenzylideneamino) benzoate on the corrosion of some metals in sodium chloride solution

Facile synthesis of Co3O4 nanoparticles from a novel tetranuclear cobalt(III) complex. Application as efficient electrocatalyst for oxygen evolution reaction in alkaline media

Enhanced corrosion resistance of mild steel in 1M HCl solution by trace amount of 2-phenyl-benzothiazole derivatives: Experimental, quantum chemical calculations and molecular dynamics (MD) simulation studies

Suzuki-Miyaura CC Coupling Reactions Catalyzed by Supported Pd Nanoparticles for the Preparation of Fluorinated Biphenyl Derivatives

Benign synthesis of quinolinecarboxamide ligands, H2bqbenzo and H2bqb and their Pd (II) complexes: X-ray crystal structure, electrochemical and antibacterial studies

Synthesis, characterization, and X-ray crystal structures of copper (I) halide and pseudohalide complexes with 2-(2-quinolyl) benzothiazole. Diverse coordination geometries and electrochemical properties

Plasma-Sprayed Photocatalytic Zinc Oxide Coatings

Facile Synthesis of Cobalt Oxide Nanoparticles by Thermal Decomposition of Cobalt (II) Carboxamide Complexes: Application as Oxygen Evolution Reaction Electrocatalyst in Alkaline Water Electrolysis

A single chemosensor with combined ionophore/fluorophore moieties acting as a fluorescent “Off-On” Zn 2+ sensor and a colorimetric sensor for Cu 2+: Experimental, logic gate behavior and TD-DFT calculations

Versatile theranostics agents designed by coating ferrite nanoparticles with biocompatible polymers

A fluorescent carboxamide ligand, having combined ionophore/fluorophore moieties, exhibiting “on-off” switching toward Zn 2+ ion

Photocatalytic Iron Oxide Coatings Produced by Thermal Spraying Process

Hydrothermal synthesis of fine stabilized superparamagnetic nano- particles of Zn(II) substituted manganese ferrite

Ni(II) and Cu(II) complexes of new unsymmetrical N2O2 Schiff bases derived from 3-(2- aminobenzylimino)-1-phenylbutan-1-one: Synthesis, structure, antibacterial properties, and electrochemistry

Synthesis, characterization and X-ray crystal structure of copper(I) complexes of the 2-(2-quinolyl)benzothiazole ligand. Electrochemical and antibacterial studies

Template synthesis, and X-ray crystal structures of copper(II) and nickel(II) complexes of new unsymmetrical tetradentate Schiff base ligands. Electrochemistry, antibacterial properties, and metal ion effect on hydrolysis–recondensation of the ligand

Syntheses, characterizations, X-ray crystal structures, and antibacterial activities of Co(II), Ni(II), and Zn(II) complexes of the Schiff base derived from 5-nitro-2-hydroxybenzaldehyde and benzylamine

Multidentate Schiff bases as new and effective corrosion inhibitors for mild steel in hydrochloric acid solution: an electrochemical and quantum chemical assessment

Intrachain antiferromagnetic exchange in a 1D branched-chain built of two different copper(II) centres interlinked by end-on azido and phenoxo bridges: electron density map, electrochemical and magnetic properties

Synthesis and Characterization of Chitosan Coated Manganese Zinc Ferrite Nanoparticles as MRI Contrast Agents

Benign synthesis of N-(8-quinolyl)pyridine-2-carboxamide) ligand (Hbpq), and its Ni (II) and Cu (II) complexes.A fluorescent probe for direct detection of nitric oxide in acetonitrile solution based on Hbpq copper(II)acetate interaction.

Synthesis, crystal structure, and electrochemical properties of Ni(II) and Cu(II) complexes with two unsymmetrical N2O2 Schiff base ligands.

Synthesis, characterization, and X-ray crystal structure of cobalt(III) complexes with a N2O2-donor Schiff base and ancillary ligands. Spectral,antibacterial activity, and electrochemical studies.

Benign synthesis of the unsymmetrical ligand N-(8-quinolyl)quinoline-2-carboxamide (Hqcq) and the varied crystal chemistry of its Cu(II), Zn(II), and Cd(II) complexes bearing acetato and aqua co-ligands.

Synthesis, crystal structure and electrochemistry of cobalt(III) carboxamide complexes with amine and azide ancillary ligands.

New Zn(II) complexes with N2S2 Schiff base ligands. Experimental and theoretical studies of the role of Zn(II) in disulfide thiolate-exchange.

Synthesis, crystal structures and electrochemical properties of CoIII complexes with hexadentate ligand containing thioether-amidopyridyl donor set

Synthesis, crystal structure and electrochemistry of cobalt(III) carboxamide complexes with amine and azide ancillary ligands Soraia Meghdadi a,⇑, Kurt Mereiter b, Mehdi Amirnasr a,⇑, Fatemeh Karimi a, Ahmad Amiri a

Synthesis, structural characterization, and antibacterial activity of mononuclear cobalt(III) azido complexes of two pentadentate Schiff bases derived from2-hydroxynaphthaldehyde.

Synthesis, crystal structure and electrochemistry of cobalt(III) carboxamide complexes with amine and azide ancillary ligands

Synthesis, crystal structure, and electrochemical properties of Cu(I) coordination polymers with two new (NS)2 Schiff-base ligands containing long flexible spacers

Synthesis, crystal structure and electrochemistry of cobalt(III) carboxamide complexes with amine and azide ancillary ligands

Synthesis, X-ray crystal structure, and electrochemistry of polynuclear azido-bridged manganese(III) and copper(II) Schiff base complexes.

Copper(I) complexes of new N2S2 donor Schiff-base ligands derived from 1,2-bis-(2-amino-phenylsulfanyl)ethane. Mehdi Amirnasr , Mahdieh Rasouli , Kurt Mereiter

*Synthesis, structural characterization, and antibacterial activity of mononuclear cobalt(III) azido complexes of two pentadentate Schiff bases derived from2-hydroxynaphthaldehyde.

A robust one-pot synthesis of benzothiazoles from carboxylic acids including examples with hydroxyl and amino substituents

Synthesis, characterization and spectral investigation of salen-type cobalt (iii) schiff base complexes. x-ray crystal structure of trans-[Co (Me-Salen)(3-Acetylpyridine) 2] ClO 4

Synthesis, X-ray crystal structure, and electrochemistry of copper (II) complexes of a new tridentate unsymmetrical Schiff base ligand and its hydrolytically rearranged isomer

Synthesis, X-ray structure, electrochemistry, and theoretical studies of palladium (II) complex with a tetradentate bis (quinoline-2-carboxamide) ligand

Syntheses, spectral, electrochemical and thermal studies of mononuclear manganese (III) complexes with ligands derived from 1, 2-propanediamine and 2-hydroxy-3 or 5-methoxybenzaldehyde: Self-assembled monolayer formation on nanostructure zinc oxide thin f

Synthesis, structure and electrochemistry of Co (III) complexes with an unsymmetrical Schiff base ligand derived from 2-aminobenzylamine and pyrrole-2-carboxaldehyde

Synthesis, and characterization of cobalt (III) complexes with Schiff bases derived from 2-hydroxynaphthaldehyde,(naph) 2 dien and (naph) 2 dpt, and monodentate amine ligands: Crystal structure, spectral and redox properties

Copper (I) Complex [Cu (ca2dapte)(NCS)] with the Flexible N2S2 Schiff-base Tridentate Ligand: Synthesis, Characterization and Crystal Structure

Synthesis, spectral and electrochemical studies of Cu (II) and Ni (II) complexes with new N 2 O 2 ligands: a new precursor capable of depositing copper nanoparticles using thermal reduction

Synthesis and characterization of Co (II) and Ni (II) complexes of 2, 5-diphenyl-3, 4-bis (2-pyridyl)-cyclopentadienone (L). X-ray crystal structures of CoLCl 2· 0.5 CH 3 CN and NiLBr 2· CHCl 3

Synthesis, characterization, solvatochromic behavior and crystal structures of complexes [CoIII (salophen)(thioacetamide) 2] ClO4 and [CoIII (salophen)(thiobenzamide) 2] ClO4

Benign synthesis of carboxamide ligands, H 2 Me 2 bqb and H 2 Me 2 bpb. Preparation, characterization and electrochemistry of Ni (II) complexes: The crystal structure of [Ni II (Me 2 bqb)]

Synthesis, characterization and electrochemistry of carboxamido Co (III) complexes: The crystal structure of [Co III (Mebpb)(N-MeIm) 2] BPh 4· CH 3 OH

{2, 2′-[3-Azapentane-1, 5-diylbis (nitrilomethylidyne)] dipyrrol-1-yl}(4-methylpyridine) cobalt (III) tetraphenylborate

Synthesis and X-ray crystal structure of the dinuclear copper (I) complex [Cu 2 ((Me-Pk) 2 En)(PPh 3) 4](ClO 4) 2· 2CHCl 3

甲醇-水二元混合物中 Co (bpb) 与叠氮离子反应的动力学研究 (英文)

New (NS) 2 Schiff base with a flexible spacer: Synthesis and structural characterization of its first coordination polymer [Cu 2 (μ-I) 2 (μ-(thio) 2 dapte)] n (1)

Structural effects on electrochemical properties of the carboxamide complexes [Ni II (Mebpb)] and [Ni II (Mebqb)]

[Bis (3-phenylprop-2-enylidene) propane-1, 3-diamine-κ2N, N′] dibromidocobalt (II)

Synthesis, crystal structure, and electrochemistry of [Co {(Me-sal) 2dien}(N3)] and [Co {(Me-sal) 2dpt}(N3)]

{2, 2′-[o-Phenylenebis (nitrilomethylidyne)] diphenolato} dipyridinecobalt (III) perchlorate

[1, 1′-Diphenyl-3, 3′-(propane-1, 3-diyldinitrilo) dibut-1-enolato] copper (II)

Kinetics Studies of the Reaction of Co (bpb) with the Azide Ion in Binary Methanol-Water Mixtures

In situ preparation, electrospinning, and characterization of polyacrylonitrile nanofibers containing silver nanoparticles

New coordination polymer based on salpn Schiff base and azide bridging ligands: synthesis and structural characterization of {Na [Co III (μ-salpn)(μ 1, 1-N 3) 2]} n (H 2 salpn= N, N′-bis (salicylidene)-1, 3-diaminopropane)

{N, N′-Bis [(E)-3-phenylprop-2-en-1-ylidene] propane-1, 3-diamine-κ2N, N′] dichloridocobalt (II)

Synthesis and coordination chemistry of new tetradentate N 2 S 2 donor Schiff-base ligand ca 2-dapte: Mononuclear and dinuclear copper (I) complexes [Cu (ca 2 dapte)] ClO 4 and [{Cu (PPh 3)(X)} 2 (ca 2 dapte)](X= I and Br)

Synthesis, characterization, and single crystal X-ray structures of [CoIII ((BA) 2en)(thiobenzamide) 2] PF6 and [CoIII (acacen)(thiobenzamide) 2] ClO4 and their solvatochromic properties

Crystal Structure of Silver (I) Complex [Ag (Phca2en)(PPh3) 2] ClO4, Phca2en= N, N′-Bis (β-phenylcinnamaldehyde) ethylenediimine

Crystal Structure of N-[(E)-3, 3-Diphenylprop-2-enylidene]-1-(4-aminophenyl) ethanone

Synthesis and Crystal Structure of Acetonitrile [N, N'-bis-(. ALPHA.-methylcinnamaldehyde) ethylenediamine] iodocopper (I)

Synthesis, structure, and electrochemistry of trans-[CoIII {(BA) 2pn}(L) 2] ClO4 complexes

Synthesis, structure, and electrochemistry of pyridinecarboxamide cobalt (III) complexes; the effect of bridge substituents on the redox properties

{2, 2′-[1, 1′-(3-Azapentane-1, 5-diyldinitrilo) diethylidyne] diphenolato}(piperidine) cobalt (III) tetraphenylborate

SENSORS PAPERS-Sensor Materials and Solid-State Sensor-Highly Selective Cyanide Coated-Wire Electrode Based on a Recently Synthesized Co (II) Complex With The

[N, N′-Bis (3-phenylprop-2-enylidene) ethylenediamine-κ2N, N′] bis (triphenylphosphine-κP) silver (I) nitrate 1.36-acetonitrile 1.64-methanol 0.53-diethyl ether solvate

Synthesis and optimization of copper sulfide‐coated electrically conducting poly (acrylonitrile) fibers

{2, 2′-[1, 1′-(4-Azaheptane-1, 7-diyldinitrilo) diethylidyne] diphenolato}(pyridine) cobalt (III) hexafluorophosphate

Highly Selective Cyanide Coated-Wire Electrode Based on a Recently Synthesized Co (II) Complex With the $ N, N^{\ prime} $-Bis (2-Quinolinecarboxamido)-1, 2-Benzene Applying Batch and Flow Injection Analysis Techniques

(1, 10-Phenanthroline-κ2N, N′)(triphenylphosphine-κP) silver (I) perchlorate acetonitrile hemisolvate

Co (III) complexes of Me-salpn and Me-salbn and the ring size effect on the coordination modes and electrochemical properties: The crystal structures of trans-[Co III (Me-salpn)(py) 2] PF 6 and cis-α-[Co III (Me-salbn)(4-Mepy) 2] BPh 4· 4-Mepy

Silver (I) perchlorate complexes of N, N′-bis (trans-cinnamaldehyde) ethylenediimine (ca2en)

(Thiocyanato-κN)(tris {2-[(3-phenylallylidene) amino] ethyl} amine-κ4N, N′, N′′, N′′′) copper (II) perchlorate

{μ-Bis [1-(pyridin-2-yl) ethylidene] ethane-1, 2-diamine-κ2N, N′} bis [iodo (triphenylphosphine-κP) copper (I)] acetonitrile disolvate

Crystal Structures of Trigonal Planer of Silver (I) Complexes [Ag (ca2en)(PPh3)] X (1: X= PF6, 2: X= BF4) with the ca2en Schiff-base Ligand

Synthesis, characterization and X-ray crystal structures of [Ni (Me-sal) 2 dpt] and [Ni (Me-sal) dpt] Cl

Di-μ-iodo-bis {[N, N′-bis (3, 3-diphenylprop-2-enylidene) propane-1, 3-diamine-κ2N, N′] copper (I)}

Bis [N, N′-bis (3, 3-diphenylprop-2-enylidene) ethane-1, 2-diamine-κ2N, N′] copper (I) triiodide

Crystal Structure of Bis (. MU. 2-azido)-tetrakis (triphenylphosphine)-di-silver (I)

Synthesis, Characterization, and X‐Ray Crystal Structures of Bis [N‐(3, 3‐diphenylallylidene) quinolin‐8‐amine‐κN, κN8] copper (1+) Tetraphenylborate (1−)([Cu (dpa‐qa) 2] BPh4) and Bis [N, N′‐bis (3, 3‐diphenylallylidene)‐[1, 1′‐biphenyl]‐2, 2′‐diamine‐κN

Synthesis and characterization of [m (bqb)](m= Co, Ni, Cu),[n (n-bu)][co (bqb)(cn)], and [n (n-bu)][co (bqb)(n)] containing deprotonated N, n'-bis (2-quinolinecarboxamide)-1, 2-benzene (bqb)–X-ray crystal structures of [ni (bqb)] and [n (n-bu)][co (bqb)(n

Poly [[(2-amino-5-bromopyridine-κN) copper (I)]-μ3-iodo]

Crystal Structure of Di-μ-iodo-bis [N, N′-bis (trans-cinnamaldehyde)-phenylenediimine] copper (I)

1-D arrays of Cu (I)-Schiff base maintained by fourfold phenyl embraces isolating diiodocuprate (I) anions

Synthesis, characterization, and crystal structures of [Ag (ca 2 en)(PPh 3)(X)](X= N 3, SCN) complexes

A novel Ho (III) sensor based on N, N'-bis (2-pyridinecarboxamide)-1, 2-benzene as a neutral ion carrier

Crystal Structure of Bis {N, N′-bis [(pyridine-2-yl) acetylidene] ethane-1, 2-diamine} silver (I) perchlorate,[Ag2 ((Me-pk) 2en) 2](ClO4) 2

Synthesis and characterization of [Cu (Phca2en)(PPh3) X](X= Cl, Br, I, NCS, N3) complexes: crystal structures of [Cu (Phca2en)(PPh3) Br] and [Cu (Phca2en)(PPh3) I]

Application of N, N′-bis (2-quinolinecarboxamide)-1, 2-benzene as an ionophore in the construction of a novel polymeric membrane sensor for the selective monitoring of the holmium (III) concentration

Crystal Structures of [Ag (bpy)(PPh3)] X (1: X= PF6, 2: X= ClO4) Complexes

Dichloro (2, 5-diphenyl-3, 4-di-2-pyridylcyclopenta-2, 4-dienone) cobalt (II)

Synthesis, characterization, and single crystal X-ray structures of [CoIII (acacen)(thioacetamide) 2] ClO4 and [CoIII ((BA) 2en)(thioacetamide) 2] PF6 Solvatochromic properties of [CoIII (acacen)(thioacetamide) 2] ClO4

(2, 2′-Bipyridyl-κ2N, N′) nitrato (triphenylphosphine-κP) silver (I)

Synthesis, characterization, and crystal structures of [Cu (ca2en)(PPh3)(X)](X= Cl, Br, I, NCS, N3) complexes

Synthesis and Characterization of Cobalt (II), Nickel (II), and Zinc (II) Complexes with N, N′-bis (Trans-Cinnamaldehyde)-1, 2-Diiminoethane Ligand,(ca 2 en): Crystal and Molecular Structures of Co (ca 2 en) Cl 2, Co (ca 2 en) Br 2 and Ni (ca 2 en) Br 2

Di-μ-iodo-bis {[bis (trans-cinnamaldehyde) ethylenediimine-κ2N, N′] copper (I)}

Thermal Deamination-anation in Cobalt (III) Thiocyanate Complexes. Novel decarbonylation of the equatorial amide ligand

Cobalt (II), nickel (II), and zinc (II) complexes with bidentate N, N′-bis (β-phenylcinnamaldehyde)-1, 2-diiminoethane Schiff base: synthesis and structures

Trans ligand influence in cobalt (III) schiff base complexes: Electronic and steric effects on the kinetics of hydrolysis

Authors Mehdi Amirnasr, Amir H Mahmoudkhani, Alireza Gorji, Saeed Dehghanpour, Hamid Reza Bijanzadeh Publication date 2002/12/15

Synthesis, structure, and electrochemistry of cobalt (III) complexes with bis (benzoylacetone) ethylenediimine Schiff base

Synthesis, Characterization, and Crystal Structures of [Cu (ca2en) 2] ClO4, and [Cu (ca2en)(PPh3) 2] ClO4 Complexes

Synthesis and spectroscopic characterization of [Co III (salophen)(amine) 2] ClO 4 (amine= morpholine, pyrrolidine, and piperidine) complexes. The crystal structures of [Co III (salophen)(morpholine) 2] ClO 4 and [Co III (salophen)(pyrrolidine) 2] ClO 4

Dyes and materials for sensitised electrochemical photovoltaics

Synthesis and structure determination of [Cu (α-L)(N 3)] NO 3 and [Cu (α-L)(NCS) 2] complexes with α-L= trans-5 (R), 7 (R), 12 (S), 14 (S)-tetramethyl-6, 13-dinitro-1, 4, 8, 11-tetraazacyclotetradecane

Adsorption Studies of Counterions Carried by the Sensitizer cis-Dithiocyanato (2, 2 ‘-bipyridyl-4, 4 ‘-dicarboxylate) Ruthenium (II) on Nanocrystalline TiO2 Films

Synthesis and characterization of 2, 5-diphenyl-3, 4-di (2-pyridyl) cyclopentadienone by thermal dehydration of 2, 5-diphenyl-3, 4-di (2-pyridyl) cyclopentandiolone in the presence of silica gel

Thermal stability of cis-dithiocyanato (2, 2′-bipyridyl4, 4′ dicarboxylate) ruthenium (II) photosensitizer in the free form and on nanocrystalline TiO 2 films

Dye and materials development for sensitized electrochemical photovoltaics

Solid state kinetic parameters and mechanism for deamination-anation of trans-[Co (III)(acacen)(amine) 2] NCS

SYNTHESIS AND CHARACTERIZATION OF AMINE (CHLORO) COBALOXIME DERIVATIVES. APPROXIMATE VALUES OF THE ANGULAR-OVERLAP PARAMETER, 0', FOR THE COORDINATED AMINES